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Road to 30% efficiency PV cells

Road to 30% efficiency PV cells

2021
EMERGING TECH

Silicon solar modules represent over 95% of global installed PV capacity with one challenger, Perovskite solar cells


SILICON SOLAR CELLS ARE LEADING THE MARKET

COMPETITIVE MARKET FOR NEWCOMERS

SIGNIFICANT IMPROVEMENT OF THE EFFICIENCY

The rapid increase in overall photovoltaic electricity production has been facilitated by the declining cost of silicon-based solar cells [29].
Due to its technological maturity, its prominence in the microelectronics industry and its cheap cost, Silicon based technology is a difficult supply chain to challenge. 
During the last decade, solar PV has seen a substantial improvement in efficiency: from 16% in 2010 to 22% in 2021. The efficiency value of silicon solar cell is moving towards the maximum achievable limit of 29.2% [29]




New concepts are being developed to overcome the physical limitations of silicon cells (efficiency, weight and intermittency) 

CONCENTRATED PV

TANDEM PEROVSKITE SOLAR CELLS

LIGHTWEIGHT PV

THERMORADIATIVE PHOTOVOLTAICS

  • Integration of tiny, highly efficient, multi-junction cells on top of standard silicon panels.
  • Use of micro-lenses and micro-trackers to track the sun’s position.
  • Measured efficiency of 29%.[32] [33] [34] 


  • Layer of perovskites absorb only the high-energy blue end of the spectrum that silicon cells are unable to capture [29].
  • Weight: 1-10 kg/m2 as opposed to 12- 15kg/m² for standard PV.
  • Encompasses several technologies: organic PV, Silicon, CiGS etc.
  • Different approaches exist such as replacing the glass with lightweight polymers. [16]

  • [35] proposes a “night time photovoltaic cell” that uses the earth as a heat source and the night sky as a heat sink.
  • [36] demonstrated a similar device that can produce 25mW/m² (for 150 W/m2 for silicon) at night using a thermoelectric module that radiates heat towards the extreme cold of space. Description of the concept [37]


  




Comparison of new concepts and materials 


CONCENTRATED PV

TANDEM PEROVSKITE SOLAR CELLS

LIGHTWEIGHT PV

THERMORADIATIVE PV

Advantages:

Advantages:

Advantages:

Advantages:

  • Assembly of technological mature bricks in an innovative module giving concentrated PV a higher module efficiency than tandem perovskite/silicon modules [34]
  • Increasing efficiency decreases the environmental footprint of PV 
  • Micro-tracking allows for a flattened production curve [34]

  • High efficiency allowing the efficiency limit of silicon to be exceeded [40]
  • High and tunable spectral performances [41]
  • Intensive R&D activity which accelerates the development [43]



  • Possible implementation of PV on unused areas/surfaces that require lightweight or flexible PV [16]
  • Already commercially available [16]
  • High-cost reduction potential due to innovative manufacturing such as roll-to-roll [16]
  • Possible production of electricity during nighttime [35] [36]
  • PV cells could be combined with thermoradiative cells [35]

Challenges:

  • Complex technology inducing an overpricing and possible reliability issues [34]
  • Gallium Arsenide (GaAs) offers high efficiency, but competitive prices must be maintained on an industrial scale [34][38]
  • Gallium is listed as a critical raw material by the European Commission [39]
Challenges:

  • Maturity not yet reached, problems with stability over the lifetime of the modules (degradation can be caused by environmental conditions) [40] [43]
  • Retaining high efficiencies on an industrial scale and module size with competitive prices [40[43][42]
  • Presence of lead in the best-performing perovskite cells might require a specific recycling process [40] [44]
Challenges:

  • Efficiency is currently lower than conventional PV modules. 
  • Adapting the best existing efficiencies to lightweight manufacturing processes [45]
  • €/Wp costs are still higher than standard PV [16]
Challenges:

  • New technology still in early research phase with a low TRL (1-3) 
  • Due to a lack of maturity, several different concepts currently exist [35][36]
  • The demonstrated power production remains low (25mW/m²) [36]


Several companies and research labs are aiming to develop the future PV technology* 

Bibliography

[29] Cherradi N., 2019. Solar PV technologies what’s next?, Becquerel Institute, Brussels, Belgium
[30] International Technology Roadmap for Photovoltaics (ITRPV) roadmap 2020
[31] ENGIE Renewables Global Business Line RENEWABLES TECHNOLOGY ROADMAP 2025 and beyond
[32] PV-magazine.com, 2019. Swiss researchers claim 29% efficiency for residential CPV panel.
[33] HYPERION Project - Panels with embedded lenses to revolutionize PV industry. 
[34] Nardin G. et al., 2020. Industrialization of hybrid Si/III–V and translucent planar micro-tracking modules. Progress in  Photovoltaïcs Res Appl., 29:819–834. <10.1002/pip.3387>
[35] Deppe et al., 2020. Nighttime Photovoltaic Cells: Electrical Power Generation by Optically Coupling with Deep Space” ACS Photonics, 7, 1?9.
[36] Raman A. P. et al., 2019. Generating Light from Darkness. Joule 3, 2679–2686.
[37] Tervo A. J. et al., 2020. Solar Thermoradiative-Photovoltaic Energy Conversion. Cell Reports Physical Science, 1-12.  
[38] Horowitz K. A. W.  et al., 2018. A Techno-Economic Analysis and Cost Reduction Roadmap for III-V Solar Cells. National Renewable Energy Laboratory, NREL/TP-6A20-72103. 
[39] EU Publications, 2020. Study on the EU's list of Critical Raw Materials. 
[40] Oberbeck L. et al., 2020. IPVF's PV technology vision for 2030. Prog Photovolt Res Appl., 28: 1207– 1214.
[41] Kulkarni S. et al., 2014. Band-gap tuning of lead halide perovskites using a sequential deposition process. J. Mater. Chem. A. 2.
[42] Li Z. et al., 2018. Scalable fabrication of perovskite solar cells. Nat Rev Mater 3, 18017.
[43] Messmer C. et al., 2020. The race for the best silicon bottom cell: Efficiency and cost evaluation of perovskite–silicon tandem solar cells. Prog Photovolt Res Appl., 1– 16.
[44] Qi Z. et al., 2018. Perovskite solar cells: must lead be replaced - and can it be done?. Sci Technol Adv Mater.19(1):425-442.
[45] pv-magazine-australia.com, 2021. Sunday read: Unlocking lightweight, flex applications.
[46] Oxford PV, 2020. Oxford PV hits new world record for solar cell.
[47] PV-magazine.com, 2021. Solliance hits 28.7% efficiency on perovskite/silicon tandem solar cell. 
[48] Solliance.eu, 2021. World record efficiency of 26,5% on a tandem solar cell based on a flexible CIGS solar cell: The architecture combines two thin-films solar cell technologies.
[49] PV-magazine.com, 2020. The world’s sunniest PV testing field.
[50] PV-magazine.com, 2017. ENGIE teaming with Heliatek to install HeliaSol lightweight technology at French school.
[51] PV-magazine.fr, 2020. Le CEA-INES et Enel Green Power annoncent un rendement de 25 % pour une cellule solaire à hétérojonction.
[52] PV-magazine.com, 2019. Hanergy hits 25.11% efficiency with HJT cell.
[53]PV-magazine.com, 2020. Panasonic claims 16.09% efficiency for lightweight perovskite solar module.  
[54] ENGIE, 2021. Q1 Results and Strategic Update, 18 May 2021
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